I have connected 1 ipod touch and i cant connect the 2nd

i have 2 sons who have an ipod touch each and there own itunes account one connects the other wont, on windows xp pc

Are you using the same USB connector cable for each?  Have you checked the second iPod's dock connector port for damaged/bent pins, or debris that may be blocking the connection?
Have you tried a hard reset of the iPod with it still connected to your PC?  To do this, press and hold both the Sleep/Wake and Home buttons together long enough for the Apple logo to appear.
B-rock

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