I have several different gmail accounts on mac mail and even when I send from one specific one by selecting it (and setting it as default!) mail gets returned to various different addresses. It seems to swich between them??

Switching between servers and accounts on mail.

It's possible that you have a problem with some outgoing servers and it's just moving through the list until it finds a working one. It will do this if you not have specific SMTP servers locked to each account?
Open Mail's preferences. Select an account and make sure it has the correct SMTP server listed. Also check the login and password for it to make sure it's correct. Check the box to use only that server for that account. Repeat this for all accounts making sure the server login and information are correct.
If an outgoing server fails in the future, you will ger a failure window asking to select another server or try again with the one chosen for that account.
You can also open connection doctor from Mail's main menu (under Window) and run the test. You should have incoming and outgoing servers listed for each account. It will tell you which are working and which aren't. You may also have intermittent failures. Run the test several times.
If this doesn't work, post back more info.

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