I just downloaded iOS 6 onto my iphone 3gs.

I no longer use this phone as an actual phone but instead as an iPod. Every time I connect to wifi I get this popup that asks me to login and loads a page that says page not found in a safari pop up.

Same problem here but I found a workaround.
Go ahead and tap on the network that you want to join
As soon as the checkmark appears next to the network jame that you are joining hit the home button.
This worked for me and I am now connected to my AirPort Express.  It would seem this is a serious bug in IOS 6 that needs to be worked out fairly quickly.  It seems like ever since OSX Lion that Apple has been turning into Microsoft with their super buggy releases of operating systems.  This is why I am still on Snow Leopard.
Anyway... Give it a shot.  Worked for me.

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