I want to delete all textures that were previously made

This Part was created and given colors in CATIA. I now imported it into Photoshop to create some more realistic textures and what not to it. Although the original textures are still there. Not sure how to just start fresh and make all new textures... basically what i want to know is if there is a way to delete these. They can all be edited but it takes time and effort to change all the names and stuff... what is your opinions?

I tried that, I exported it with no materials... it was just default colors, but when I put it back into Photoshop it now just gives every part the same material.. basically I just want to know if there's a way to give individual parts a new material in Photoshop. Is that possible? New screen shot of what it looks like below.

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