I would like to give my old iPhone to a friend who would be on a different carrier, is this possible?

I have recently upgraded to the iPhone 6 and would like to give my old iPhone 4S to a friend in Argentina. Can i do this, if so how? Would his carrier just put their SD card in the side?

It's very unlikely.  Here are at least some of the conditions you would have to satisfy.
Ask the original iPhone 4S' cellular carrier if they will unlock the iPhone.  If their answer is "no", you are finished and cannot proceed.
If the original carrier would unlock the iPhone, you would have to do this before passing it to your friend.
Check Settings > Genreal > About > Model and record the model number you see.
Ask your friend to contact their cellular carrier to find out if they support that particular model.

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