I would like to use the F19.....

I would like to use the F19 to have my calculator pop up on the screen, can you help me make that happen?

Keyboard short cuts can not be set to launch Apps.
OS X Mavericks: Create keyboard shortcuts for apps
There are many apps in the App Store that claim to do this. Though I have no first hand experience.
Search for hotkeys on the App Store.
Though if you are happy using Automator here's a guide to Setting Launch App.
http://computers.tutsplus.com/tutorials/how-to-launch-any-app-with-a-keyboard-sh ortcut--mac-31463
Hope this helps.
PJRS

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