ICloud is not working in iphoto, iCloud is not working in iphoto

Hi,
I am having difficulties with installing iCloud 9.5.1. on my iMac from 2007. I have updated all operating systems, but still iPhoto is not working properly. The main reason why I wanted to upgrade from iPhoto '08 to iPhoto 9.5 is the iCloud feature. So all my pictures taken with my iPhone are synced to my iMac. Here lies the problem, I cannot check the iCloud box in the preferences of the installed iPhoto 9.5.1 Neither can I check the option to use iCloud under the iCloud tab in the iPhoto overview.
I have reinstalled iPhoto several times, cleaned it from the OS via CleanMyMac, but still is not working.
I used to use an WD external harddrive as my library, but not anymore. Maybe there is still a hidden path somewhere in my computer referring to that old location? I have made a new local library on my iMac, but also this did not resolve the problem.
I can import pictures from a local folder, or iPhone to the newly installed iPhoto. Although this takes quite some time, this part of the program seems to work.
Anybody some good advice? I don't know anymore where to find the problem.
Many thanks in advance!

I cannot check the iCloud box in the preferences of the installed iPhoto 9.5.1 Neither can I check the option to use iCloud under the iCloud tab in the iPhoto overview.
You do no say how the System Preferences "iCloud" options are set.
Have you clicked the "Options" button besides Photos in the System Preferences iCloud and enabled  "My Photo Stream"?
You have upgraded to MacOS X 10.9.3, if you are using iPhoto 9.5.1, right?

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