If i want to texture one of my 3D models in 3D-s max, should I be using Illustrator or photoshop

just want to know what components of a texture (specular, diffuse, colour etc..) i create in which program

Whichever you like. 3D programs do only rasterized images, anyway, so even if you work in AI with vectors, you have to export as PNG, TIFF or whatever. And since many of your textures will be based on photos, anyway, PS obviously is an easier choice...
Mylenium

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