IMessage sending to someone who has iMessage turned off

Hi,
My girlfriend has recently turned iMessage off as so many messages I was sending to her were failing. I have no problem with anyone elses iMessage.
Now that she's turned it off, my phone still tries sending her iMessages, they just never reach 'delivered' status, and also never fall back to SMS, even though I've got this feature enabled.
Try deactivating and reactivating my iMessage, but problem still persists!
At the moment I'm just having to hold the undelivered iMessage and manually send as text message for most messages.
Any ideas?
Cheers,
Dan

Always phone number.
Her email address (which is also her apple id) is in her contact card under 'email' but I always message to phone number.
I message to phone number with every other contact as well. People with ios5 and iMessage turn on, I can iMessage perfectly. People with ios5 and iMessage off, it always sends an SMS first time.
It's just this one contact that seems to be the anomaly.

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