Internet Accounts preferences can't connect to the account -

Updating 17th October to Yosemite and working fine until 3rd November.
Mail was suddenly not able to connect to one of my external hosted e-mail accounts. Another account, same external virtual hosting but other domain, username, pwd is still working fine. Account settings in Mail are exact the same for both accounts (IMAP and SMTP). It's now a week trying to find the problem without any result. Very strange is, that Mail is sometimes suddenly able to connect the invalid account: Last week if I was away from the Mac for 20 minutes, coming back, the account was online. I was able to do some mails and cleanup my inbox. It ends if i reboot the Mac. In my network all Mavericks Macs, iPhones, iPads are connecting well this account.
I did a Mail setup just with the invalid account in a clean Guest User. No chance to connect the invalid account. Adding the other working one was just a thing of seconds.
I found that in System Preferences > Internet Accounts for the invalid account a pop-up asks for "Enter the password for …". Doing so it comes up with "Unable to verify account name or password" with the only chance to Cancel. I think there must be a starting point to my problem.
Is anyone knowing about this? Any help is very welcome.

I'll pass this along to all. I have the same smtp issue. I have two Cox email accounts and a number of Gmail accounts. The Cox smtp server goes offline. Gmail is fine. Yesterday I began pressing every button and the following worked, why, beats me.
Open MAIL got to MAIL PULLDOWN then PREFERENCES then ACCOUNTS then SELECT THE EMAIL ACCOUNT and look at ACCOUNT INFORMATION - now at the bottom hit the ARROW at OUT GOING MAIL SERVER (SMTP) which brings up a list of severs SELECT EDIT SMTP SEVER LIST. now this bring up a list of servers  HIT THE ADVANCED BUTTON which brings the properties of the highlighted server below. LOOK AT THE TWO PORT BOXES.
The first selection says USE DEFAULT PORTS (25 465 587)
The second selection asks you to ENTER CUSTOM PORT.
FOR COX: The Cox website says to use port 465. I SELECTED CUSTOM PORT AND ENTERED PORT 465 and exited Preferences AND IT WORKED!!!
So far so good today.
I have no idea whether this has any relevance to the rest of you using other email servers so good luck.

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    # file so it has a .ovpn extension #
    # Specify that we are a client and that we
    # will be pulling certain config file directives
    # from the server.
    client
    # Use the same setting as you are using on
    # the server.
    # On most systems, the VPN will not function
    # unless you partially or fully disable
    # the firewall for the TUN/TAP interface.
    ;dev tap
    dev tun
    # Windows needs the TAP-Win32 adapter name
    # from the Network Connections panel
    # if you have more than one. On XP SP2,
    # you may need to disable the firewall
    # for the TAP adapter.
    ;dev-node MyTap
    # Are we connecting to a TCP or
    # UDP server? Use the same setting as
    # on the server.
    ;proto tcp
    proto udp
    # The hostname/IP and port of the server.
    # You can have multiple remote entries
    # to load balance between the servers.
    remote my.server.com 1194
    ;remote my-server-2 1194
    # Choose a random host from the remote
    # list for load-balancing. Otherwise
    # try hosts in the order specified.
    ;remote-random
    # Keep trying indefinitely to resolve the
    # host name of the OpenVPN server. Very useful
    # on machines which are not permanently connected
    # to the internet such as laptops.
    resolv-retry infinite
    # Most clients don't need to bind to
    # a specific local port number.
    nobind
    # Downgrade privileges after initialization (non-Windows only)
    user nobody
    group nobody
    # Try to preserve some state across restarts.
    persist-key
    persist-tun
    # If you are connecting through an
    # HTTP proxy to reach the actual OpenVPN
    # server, put the proxy server/IP and
    # port number here. See the man page
    # if your proxy server requires
    # authentication.
    ;http-proxy-retry # retry on connection failures
    ;http-proxy [proxy server] [proxy port #]
    # Wireless networks often produce a lot
    # of duplicate packets. Set this flag
    # to silence duplicate packet warnings.
    ;mute-replay-warnings
    # SSL/TLS parms.
    # See the server config file for more
    # description. It's best to use
    # a separate .crt/.key file pair
    # for each client. A single ca
    # file can be used for all clients.
    ca ca.crt
    cert host.crt
    key host.key
    # Verify server certificate by checking
    # that the certicate has the nsCertType
    # field set to "server". This is an
    # important precaution to protect against
    # a potential attack discussed here:
    # http://openvpn.net/howto.html#mitm
    # To use this feature, you will need to generate
    # your server certificates with the nsCertType
    # field set to "server". The build-key-server
    # script in the easy-rsa folder will do this.
    ns-cert-type server
    # If a tls-auth key is used on the server
    # then every client must also have the key.
    tls-auth ta.key 1
    # Select a cryptographic cipher.
    # If the cipher option is used on the server
    # then you must also specify it here.
    ;cipher x
    # Enable compression on the VPN link.
    # Don't enable this unless it is also
    # enabled in the server config file.
    comp-lzo
    # Set log file verbosity.
    verb 3
    # Silence repeating messages
    ;mute 20
    Anyone have any idea what could be going on? It seems to me that when a program starts up it takes a snap shot of the current network status and it then uses it, even if it's 10 minutes later and the network has been fully loaded/configured, the program uses that snap shot and can't connect to the DNS.
    Last edited by anEveryDayGuy (2013-05-02 21:20:47)

    'Requires=network.target' wasn't in it so I added it but nothing's changed. I've left it in because openVPN does require network.
    As I said, I had this problem with a script so I don't think it's anything specific to openVPN. I had a weird occurrence this morning however. When I started the computer up this morning  openVPN worked just fine. However when the computer rebooted openVPN couldn't resolve the host address again.

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