IPhone 4 receiving e-mail, but not sending.

So i posted another topic in the 3G S forum because i was having issues with iOS 4 on the iPhone 3G S - it was not able to send or receive e-mail and all settings were intact and left unchanged - everything worked prior to iOS 4.
Now, i have the new iPhone 4, of course with iOS 4 on it too...and i am receiving my e-mail now, but now i cannot send e-mail.
It keeps telling me to enter a password but when i go into the Mail, Contacts, & Calendars settings and look at each individual e-mail account - all have passwords on them. All passwords are correct, but i went through a second time just to be sure and entered in each individual password to each account again just to make sure they all had passwords.
I am still unable to send e-mail but i can receive it now.
Is this an iOS 4 issue?
Any help is much appreciated - thank you!

I did try removing the accounts (i have about 20 different ones that i manage)...then i tried to "Sync Mail Accounts" through iTunes - the accounts that i wanted - and i was still having a few glitchy issues with sending or receiving e-mail when they got back on.
So i un-checked the sync mail accounts, and deleted them all individually off my iPhone and then added them all one by one all over again - right now it seems to be working fine but it did not download all of my existing messages that should be there so basically i am starting with an empty inbox on all my accounts.
I'm just forwarding all the important ones off my computer to the same e-mail so i can retrieve them on my iPhone then. So far everything is working.

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