IPhone complains about email password for non-existent account.

I upgraded from my 1st gen iPhone to a 3Gs the other day.
Now when I try to send email, I get an error stating that "Cannot Send mail.no password provided for "iat""
link to the screenshot.
http://filebin.ca/mukgzm/IMG_0309.jpg
I've not had an "iat" email account on my phone since before September 2008, and even then, it was never set up properly as the mail-server wasn't allowing IMAP connections from outside, so it was deleted before it was working.
My default SMTP server is my own server, on it's own domain (vehentis) and my secondary is my work email server. Nowhere in my mail settings does the word IAT even appear.
Anyone got any ideas?

The account has been completely deleted, yes.
I don't syncronise my email accounts in iTunes, as I have my own IMAP email server and run thunderbird on the macbook. I don't, however, recall seeing any email account settings at all within iTunes.
My email accounts are set to check on a 15 minute basis, and I'm often checking both accounts more frequently than that.
As for power-cycling the phone, I received it on Tuesday. Activated it and set it up from a backup of my old iphone which had been taken on Friday, and it's been reset twice since then. It's rarely powered down as it sits in the desk cradle at work, in a cradle on my bedside table at night, and is in my pocket the rest of the time.
a

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