Is there a difference between saving a word doc with images as a pdf or printing to pdf?

Is there a difference between saving a word doc with images as a pdf or printing to pdf. Images are sometimes missing when the document is  saved as a pdf or they are visible to the document owner but seem to disappear when viewed after submission to grants.gov. and proposal Central.
Using Acrobat 9.5.5 and Office 2010 and Office 2011 Mac

Is there a difference between saving a word doc with images as a pdf or printing to pdf. Images are sometimes missing when the document is  saved as a pdf or they are visible to the document owner but seem to disappear when viewed after submission to grants.gov. and proposal Central.
Using Acrobat 9.5.5 and Office 2010 and Office 2011 Mac

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