Issue with sending email from the iPhone

I'm still new at this iPhone thing so I may be missing something. When I first got it I turned Wi-Fi on and had been using it for two weeks. Then I figured out that when I turned Wi-Fi off the phone reverted to EDGE for data. The issue is that I can receive email with Wi-Fi turned off but for some reason when I try to send email it tells me it can't contact the mail server. As soon as I switch Wi-Fi back on the emails send. Why would it do this?

http://docs.info.apple.com/article.html?artnum=305634

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