Mail has stopped sending via exchange account after syncing with Mobile Me

Hi There,
I'm having trouble tracking down the cause of this issue, but after resetting sync data on two macs (10.6.7) neither can send emails using our work account (iPad and iPhone seem fine).
When I reply to emails for work (on a third-party hosted exchange server) I receive an error saying that it can't send and suggests choosing another server. The only server in the list is Mobile Me which has the word (offline) next to it.
1.
Should the exchange server appear in the list of available servers?
2.
It looked like Mail was trying to use mobile me to send the work emails but was failing because it rejected the address, so I deleted mobile me from the SMTP server list in an effort to force mail to use the Exchange server but no joy.
The connection doctor sucessfully connects to the exchange server so it obviously sees the connection and the exchange account is set to only use the exchange server (it appears in the dropdown but not in the edit servers list).
Has anyone else seen this - need to send a few work emails!
Any help would be much appreciated.
Cheers
Ben

Never Mind got it... I did find the answer after a bit more searching Thanks to anyone who read the message...

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