Mail in 10.6 fails on send

I have a new 10.6.1 Server and I use IMAP/SMTP & yes I have POP turned on but do not use it at this time.
My webmail works wonderfully. Send & receive both work with no problems.
My mail server's name is in the form of: mail.domain.net Mail is on a standalone CPU. Web-hosting is a different CPU. The DNS should be fine as I am replacing a 10.5.8 OS-X Server and the mail server does not do DNS. I do have alias records set for domain.net so when someone sends email we do not have to have a "mail." as part of our email addresses.
I can pick up email but I can not send email? Anyone have a couple of places I should check?

I used Text Wrangler to see hidden files and opened etc/postfix/master.cf
Saved a copy of course and then uncommented the line that starts with:
submission inet - n

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