Mail - outgoing mail won't send over 3g

Recently upgraded from the original iPhone (1st gen) to iPhone 4s.
I have always used Windstream email on my iPhone with no problems, both incoming and outgoing, both wifi and edge (on previous phone.)
With my new 4s, my outgoing mail works fine when I am in my home wifi, but it will not send when away from home and using 3g.
I have contacted Windstream (the ISP) and they only stated that as far as they can tell, my settings are correct, which are:
Outgoing Mail Server
Host name: smtp.windstream.net
User name: [email protected]
Password: (password)
Use SSL: off
Authentication: password
Server Port: 587
Thanks for any hints.

Thank you for the suggestions.
Yes, I have my userid and password saved in the settings for smtp.windstream.net.
I added smtp.sprintpcs.com as a secondary SMTP server. it is on and SSL is off. I do not have a userid and password for the sprint smtp server. I have tried both server ports 25 and 587. Unfortunately, I am still getting the error when trying send mail over 3g.

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Here is an article that will help walk you through some troubleshooting steps for this issue:
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Hi,
My mail won't send on my laptop. There is spinning next to "Send" but the message remains in the outbox.
I deleted and readded all email accounts. This did not solve the problem.
I started a chat with Apple Express support and they said that Lion doesn't support Apple mail so they couldn't help.
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