Mail problem - "Sender address was invalid"

So I get this message from time to time: then I try to send an e-mail from the mail app on my iPod Touch, it'll come back to me saying "The Sender Address was invalid" and won't send it. However, it's gotten worse of late; previously, I would hit the refresh button and then it would send, but recently that has stopped working. For about 45 minutes this morning I tried to send an e-mail and it just wouldn't send. I ended up having to log into my e-mail manually (through Safari on my iPod) to get it to send (which worked). However, I would like to know if anyone else has encountered this problem, if anyone knows what causes it, if anyone knows how to solve it, and if it would be worthwhile submitting a bug report to Apple about this. Thanks.

With so many threads and indy websites posting this problem, I'm not sure where's best to post my solution. So it's here and I hope someone gets help from it.
Same thing - "sender address blah blah blah" and none of the fixes worked. So I deleted the outgoing server (or so I thought!) and restarted the iPod. The server was not listed.
Then I reentered the information and used Port 25 (I had tried that before but went back to the default port of 587 before deleting the old server).
I connected to my WiFi and my mail went thru immediately. But what was interesting was the 'old' server showed up as the backup with port 587. I don't dare touch a thing - it's working!
BTW, I am using my own website and mail servers (hosted elsewhere).
Interestingly, if the iPod is accessing the mail servers, the computer access is blocked. Probably my host no allowing multiple connections from the same location, but I've done that before with my laptop and other Macs here w/o a hitch. But really a big deal, but interesting.
Thanks to all who have posted in this thread and all the other threads. Together, we ARE tech support! But the Apple guys and gals are great as well. And this iPod Touch is AMAZING!

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