Mail sends via Hotspot connection but not when connected to wifi

Hi guys and girls,
Really hope you can help. I have the new iPad 3 wifi only. When connected to wifi at work, home or a friends I can recieve mail absolutely fine however if I reply or try to send an email it will not send and I recieve an error message.
However, if I disconnect from the router at work home or at a friends and turn my iPhone into a hotspot using 3G network and connect my iPad to this then mail sends perfectly??
Any suggestions would be great!
Regards
Mark

What is the error message?
Who is the email account provider for this email account and does the email account provider have an authenticated SMTP server?

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Mail sends via Hotspot connection but not when connected to wifi

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