Mail sent from POP 3 account going out via Exchange

I have an original iPhone running the 2.0 software. I have it configured for a corporate email account via Exchange as well as a POP3 personal account.
When I send an email from the iPhone via the POP3 account, it ends up going out via the Exchange account and showing up in the Exchange "sent" folder. While I'm composing the message, the From field shows the POP3 address. Still, once the message is sent the From field shows the Exchange address.
I've searched for settings that might affect this, but find none. Is this a feature or a bug?

This should not be happening. The iPhone includes a default email account selection, but that is not in play with this, or shouldn't be.
I suggest deleting and recreating the POP account on your iPhone.
This will lose all sent messages - those currently in the POP account's Sent mailbox.

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