Mail SMTP server not accepting password. Works on all other clients.

I am having issues with Mail and sending emails. Firstly I would like to say I have set this account up on Outlook 2011, Thunderbird and also Outlook PC and I can send and recieve with no problems.
On Mac mail I can recieve emails perfectly.
The account is set up with an SMTP Server. Our server requires authentication therefore I supply my username and password in there too. When I try to send an email mail says the server has rejected the password and asks for the correct password. The password I put in is correct, as it is the same password I have used on the other clients.
So there is something that Mail doesnt like when it comes this server and I cant work out what it is.
The only thing I thought of is that my password is all numbers. Could that make a difference?
Any ideas?

andrewrob,
I had the same problem and found that I had to unlock CAPTCHA here: http://www.google.com/  accounts/DisplayUnlockCaptcha.
This worked for me. If that doesn't work, you could try this:
1. Open Keychain Access (located inside the Utilities folder which is inside the Applications folder)
2. Highlight the login keychain in the white box to the left.
3. Click the lock above it to lock the login keychain.
4. Now unlock it.
5. Go back to Mail and enter your password again. You will probably have to do it once for incoming mail and once for outgoing mail.
I hope this helps!

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