Mail wont send emails - Help!

Hello!
Unable to send emails from my Mac (G5 OSX 10.5.8) using Mail.
Dialogue box says "Verify that you have addressed this message correctly. Check your SMTP server settings in Mail Preferences and verify any advanced settings with your system administrator."
Email addresses are fine (in use for years) and smtp address is good too.
Receiving incoming emails without problem.
Connection Doctor shows all is good for my 3 PoP accounts.
Problems started on returning from overseas trip. Abroad I use a Mac Pro which I upgraded to snow leopard. I also use MobileMe. The Mac Pro had issues sending mails too - using connections which had worked faultlessly for years. Had to restart it to send emails waiting in Outbox.
Any fixes or help for me?
Thanks for any responses
Cheers

Is the problem that Mail will not send ANY emails or that you cannot Reply to some emails.
If the former, look at your SMTP settings (not just the SMTP address) to ensure that your port number and authentication type are correct for your current ISP. Being abroad might have reset these.
If the latter, look at the "Send To address" which Mail has infrequently corrupted since Panther.
Sometimes if you Reply to an email sent from: <[email protected]>, Mail creates the corrupted address: "[email protected]><[email protected]" <[email protected]> which will not send successfully.

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