Mails getting bounce back from only one account,why?

Hi Every one,
I have a strange problem, I'm using postfix mail server and LDAP directory service.
From last few day I'm facing strange problem. Like I have 15 user account configured for accessing emails.
In that, only one user gets bounce back messages. I found the issue but not sure how to fix it.
Issue:
If I stop the (LDAP) directory and mail service and restart my Leopard server and services. I can send emails through. But after few days or a week later i have to face the same issue.
Help Please
Thanks,
Gulab Pasha

If you right-click on an accont's inbox and select "Synchronize {name}", that should perform the "get new mail" function as part of the general synchronization.

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