ME32L Material Group change

Hello Guys,
In transaction 'ME32L' - agreement, I can see some line's Mat. Grp were '0000'.
when I use mm02 change some material's Material Group and come back to see in the ME32L.
The Mat. Grp have no change.
Can some guys know what is this probelm? And how can I change agreement Material's 'Material Group'?
Regards,
Alex.

Hello yogesh, sudhansu,
Thank you for your reply.
Because I accept SAP just two weeks, so many concept not very clearly..
At present, I suggest our Purchasing Department delete the old 'agreement' line, and recreate 'agreement' new line for these materials.
I think these will be help them. @_@
These days is Christmas holiday and new years holiday, most of SAP specialists were not in the company.
Just I, only touch SAP two week's newcomers.. Very difficult.
By the way, thanks again for everyone's help.

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