Mission Control / Spaces keeps opening in a new desktop - can't edit this

Anyone else find that Mission Control / Spaces will keep moving over to Desktop #2 for certain apps - even when they are assigned to main desktop?
Annoying!

Just to update.
I re-booted from the old starup volume, which is still intact. ( for now).
I was able to create a new library from there and the mail was alos able to attach files.
Started up from the new volume anf Aperture was able to be poinrted to the new Library.
I am thinking I may need to reinstall both the Mtn Lion and Aperture to resolve this.  Unless someone has a suggestion.........
I might alos add that I can't sign in to this forum on the new OSX. 
I looked at the password and username stored in the old passwords list and it is not using the @gmail.com for my user name.
I tried leaving it off the sign in on the new OSX but it won't take it.  If I use the @gmail I get the screen to sign in a second time for security followed by a screen to create a username, which can't be done becuse that email already has a username.  
I may have to create a new Apple ID also, f I want to use this forum.
Apple tech support said to file a report.  Which I did.
Message was edited by: Michigan One Fly

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