My iTunes Library is having trouble with a NAS on power schedule

Hey everybody,
This problem is going to be difficult to translate into words.. here goes..
I have a mac, a NAS box, and Apple TV. Everything is hardwired wired to a gigabit LAN.
I have itunes on my mac, with itunes manageing my content on the macs internal HDD (so I can drag and drop music into itunes and itunes sorts it out by its self, also so I can just listen to music whenever).
The tricky part is... I have a NAS box with all my movies (music is local on my mac) that is on a power saving schedule. All of this content has gone though iFlicks (this program rocks!) and is in itunes format. While holing "option" I drag and drop my movie content into itunes. Allowing this content to stay in its current location BUT being added to my itunes library AND still letting itunes do its automatic thing when I drag and drop to add music.
The reason the NAS is on power saving is I work during the day and only watch content at night so why not save the very little amount of power it would use and not leave the HDD spinning all day everyday.
Now this where everything turns bad. Its not uncommon for me to get up early and listen to music or come home for lunch and fire on some tunes. It seems that when the NAS is off and I open itunes to play some music somehow itunes looks for the movies in its library, which it cant find because the NAS is off. Soooo itunes puts a little "!" next to the movie it cant find, and progresses through the movie collection making all of my content unavaliable through my apple tv when I do sit down to watch something regardless of the NAS now being on and the content definatly being there.
The solution I have found to this problem is to select all of my movies and tv shows delete them and then re-add them as I have explained (takes about 15mins to add everything, this is only with a small 3% used of my 6TB avaliable)
Am I missing a tick box for itunes to recheck that the content it didnt find is definatly not there? Or is there some smart work around? Whats the go?
Hopefully this kind of made sense!
Thanks in advance.

Hi Hypronic101,
If your mother's iPhone is unexpectedly shutting off, even when there appears to be battery charge left, you may find the troubleshooting under the Power/Battery section of the following article helpful:
iPhone: Hardware troubleshooting
http://support.apple.com/kb/ts2802
Regards,
- Brenden

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