My iTunes won't sync and I can't download an app onto my iPhone 4S. It's been really bad since the update!

Hi,
Two problems here guys
1. My iTunes won't sync. Since the update to iTunes 11 it refuses to transfer purchaces from my iPhone 4S and won't put stuff from my phone into my iTunes library and I can't put anything on my phone through my laptop. Both the laptop and the phone say that they are syncing but nothing actually happens
2. As the Avengers Initiative app is currently free I decided to try and download it straight on to my phone, but every time I try it says I don't have enough memory, even though I deleted stuff especially so I could download this and I now have 3.6 GB free, so I downloaded it on to my iTunes on my computer, but of course my iTunes won't sync
I've reinstalled iTunes twice and it hasn't worked!
Somebody help please

Same problem, any assistance would be appreciated.
thanks

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