New SMTP server has SSL. One of two Ethernet networked Macs works, the other doesn't. Help!

We changed from Optimum to Verizon FIOS today. We have two Macs connected by Ethernet. The Mini running Mavericks and Thunderbird 24.6 was able to set the outgoing server as smtp.verizon.net on port 465 with connection security SSL/TLS with no authentication and it works fine.
The other Mac is an ancient G4 running 10.3.9 and TB 2.0.23 and it does not accept running without authentication.
With optonline, we ran on port 25 with no authentication.
I tried putting in the user name and pw we entered on verizon.net, and that doesn't work. I tried the user name and pw from our pop mailbox, and that doesn't work. BTW, the incoming mail is working fine on both computers.
What's going on? How do we fix it?

But I don't know what user name and password to enter. When I enter the username and password from my Verizon account on the 2nd linked computer, it does not recognize it. Does it have to be entered on both computers? What do we select on the 1st computer running Mavericks? Normal password? Then do we enter our Verizon username and password?

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