No sending of mail possible

Hello,
I have a problem with a mail account on my Mac (Mac OS X.4.6).
My wife has an account on my Mac so that we can both use the Mac via fast User Switching. No problems so far. But last week she was not able to send mails anymore. Recieving is possible.
But if she replies to a mail or writes a new one the menu where you can select over which mail account the mail shall be sent is empty. But in preferences a mail accounts are visible and active.
Replying to a mail opens a mail window but without contents. No text of the original message is displayed.
What could be the problem?
Does it help to remove the preferences plist-file?
Any help appreciated.
Regards
Michael.

Yes Michael, that would be a good starting point.
Open Preferences from within the Mail program and note the exact settings for your email accounts.
Quit Mail
Drag the following file to the desktop:
your wives' home directory / Library / Preferences / com.apple.mail.plist
Restart Mail
Re-install your mail settings for at least one account
These actions will not interfere with your mailboxes, it will simply create a new plist preference file when you re-start Mail.
If that did not help, you can place back the .plist file so you have all your account settings back.

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