One of four email accts will not send mail

I have a Z. Tablet. I set up four of our business email accts and all will receive mail but one will not send mail. Tried many combinations of smtp addresses but no joy. Consulted my email provider tech guys. They set up using same on another android device and worked for them. They have given up on solving this. It just happens this is the most important mailbox. Anyone offer help to solve?

What if you use a different email app? perhaps Moxier, K9, Maildroid?
"I'd rather be hated for who I am, than loved for who I am not." Kurt Cobain (1967-1994)

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