Optimum Online does not recognize email addresses for sending mail

We just got the new iMac for our family. I decided to junk eudora and use apple's mail client. I have 3 accounts: mine (admin), my wife, my son. My wife and son can both receive mail via Mail but they cannot send. My son gets "This message could not be delivered and will remain in your Outbox until it can be delivered. The server "mail.optonline.net" rejected the address "Gregory Sohanchyk" " I reinstalled eudora so my son can send and receive. Queried cablevision but have yet to receive a response. Any one else having problems with other accounts and cablevision and optimum online.

Pull your mail plist from ~/Library/Preferences

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