Outlook 2013 - MS Outlook has stopped working... (sending Email)

Hi everyone, this one is extremely frustrating and hoping you can help.
My colleague has Outlook 2013 running on Win7 Pro. There are two different mail account, both Exchange server.
Everything works fine except Sending mail. Every time we attempt to send an Email Outlook crashes with the following error:
"Microsoft Outlook has stopped working... A problem caused the program to stop working correctly. Windows will close the program and notify you if a solution is available"
I say every time, but it has occasionally sent Email. Never more than once after starting up Outlook and most often, never.
The accounts work for using OWM. The accounts work fine configured identically on a different PC.
Tried Safe Mode. No help
Uninstalled all AV software. No help
Ran Office Repair (both Quick and Full). No help
Short of completely uninstalling Office, re-installing and recreating the profile from scratch (which I would like to avoid) I'm not sure what else to try!
Any suggestions would be most appreciated.

Hi,
In case there's a corruption in your Outlook Data File, please try to repair the data file(.pst or .ost) and check the result:
http://support.microsoft.com/kb/272227
If you have setup two different Exchange Accounts in one Profile, please try to remove one from the profile, create a new profile to setup the account.
http://support.microsoft.com/kb/829918/en-us
Check if the issue persists with two different Profiles.
Regards.
Melon Chen
TechNet Community Support

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