Photoshop CS6 files saved to User/Library/Caches/Temporary Items

Question

Many of the users on my school network cannot save their Photoshop files to a specified folder. Instead the files are automatically saved to User/Library/Caches/Temporary Items folder.
I've changed the File Handling Preferences with no results in changing this issue. Since a couple users did not experience this problem, I'm wondering if it might be a permissions problem.

Answer 1

With the new versions, you have to be more precise with Folder redirection :
com.apple.MCXRedirector
[dict] Always
[array] LoginRedirection
[dict] 0
[string] action deleteAndCreateSymLink
[string] destPath /tmp/%@/Library/Caches/Adobe
[string] path ~/Library/Caches/Adbobe
[dict] 1
[string] action deleteAndCreateSymLink
[string] destPath /tmp/%@/Library/Caches/Adobe Camera Raw
[string] path ~/Library/Caches/Adbobe Camera Raw
[dict] 2
[string] action deleteAndCreateSymLink
[string] destPath /tmp/%@/Library/Application Support/Adobe
[string] path ~/Library/Application Support/Adobe
[dict] 3
[string] action deleteAndCreateSymLink
[string] destPath /tmp/%@/Library/Caches/Meta
[string] path ~/Library/Caches/Meta
[dict] 4
[string] action deleteAndCreateSymLink
[string] destPath /tmp/%@/Documents/Données utilisateurs Microsoft/Office 2011 AutoRecovery
[string] path ~/Documents/Données utilisateurs Microsoft/Office 2011 AutoRecovery