Photoshop randomly not applying Lightroom-generated .xml files

Hi there.  I have a problem with Photoshop or Lightroom.  This has happened to me before, but it's just somehow resolved itself previously.  This time it won't.
I'm using LR 2.7 and PS CS4 and CS5.  I've edited a bunch of Nikon RAW files (NEF) in LR and then saved the metadata to the files, but when I open the images in Photoshop the edits are not applied.  It's like I haven't made any changes at all to the RAW files.  For some reason this only happens to a few images, seemingly at random.  I can't tell which ones without opening them all individually in Photoshop, though.
I have a script that I run in Photoshop that creates PSDs from my edited RAW files and applies some quick Photoshop adjustments as well, so exporting the files from LR isn't a solution for me.
I'm using a Mac Pro with Leopard 10.5.8.
Any ideas?  Thanks.

In the normal situation, LR needs to see a PS installed for it to detect the Edit In PS option is possible, so if you uninstall both, then install PS, first, then LR.  Of course with this release there may be some hiccup that requires installing either one or the other, again, but if you've uninstalled both and are reinstalling both, then install PS, first.

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