Problem resetting user permissions- CMD R not working

Hi,
Thanks in advance to those willing to lend some help!
GEAR:
2.53 GZ Core 2 Duo Mini running 10.8.5 All updates done.
I believe I have a current Time Capusle backup at my disposal.
New Macbook Air available to help.
ISSUE:
In the last couple of days I seem to be losing permissions to do things in my user profile which is the admin. Can't dump anything to trash without a password, mail will not open as it doesn't have permission anymore, can't move files around from folder to folder, Excel won't save as it is now read only, Firefox won't open as it thinks there is already an open version...Messages won't sync properly anymore or access address book to bring up peoples names to match the phone numbers... etc..etc.
Research showed the problem is likely user permissions and the cure is resetting. Knowing this has to be done via terminal after a COMMAND  R boot into recovery mode I have tried everything to make this happen. No go! Apparently the partition required to boot into recovery never happened during install as the computer insists it is not there. Worse it will not default to internet recovery either. When I hold OPTION and boot I have only the HD visible and no recovery option to choose from.
I have created a 10.8 USB recovery stick (on my mac air) and can boot to that on the mini but there is no terminal option (as far as I can see) to allow me to reset the permissions. I also tried to boot to an old Leopard CD hoping that might work.. nada.
I have done a verify disk and repair disk permissions. All good. The computer works 100% fast and proper if I login under a new user profile so my issue appears not to be hardware related at all.
Given that I can't CMD R into any recovery is there any other way to reset these permissions?
Anyone know what would cause this to happen?
Thanks!!
Dave.

In light of the fact there are other things Etre noted as issues I posted the lot. Sorry it's longer but thought I may lead you in the correct direction.
EtreCheck version: 1.9.13 (49)
Report generated 13 August, 2014 11:05:31 PM EDT
Hardware Information: ?
  Mac mini (Late 2009) (Verified)
  Mac mini - model: Macmini3,1
  1 2.53 GHz Intel Core 2 Duo CPU: 2 cores
  8 GB RAM
Video Information: ?
  NVIDIA GeForce 9400 - VRAM: 256 MB
  Acer H233H 1920 x 1080 @ 60 Hz
  Acer H233H 1920 x 1080 @ 60 Hz
System Software: ?
  OS X 10.8.5 (12F45) - Uptime: 0 days 1:45:51
Disk Information: ?
  ST750LX003-1AC154 disk0 : (750.16 GB)
  S.M.A.R.T. Status: Verified
  disk0s1 (disk0s1) <not mounted>: 209.7 MB
  Mac Mini HD (disk0s2) / [Startup]: 749.81 GB (467.41 GB free)
  PIONEER DVD-RW  DVRTS08 
USB Information: ?
  LEXAR ImageMate RW022 Reader 15.93 GB
  S.M.A.R.T. Status: Verified
  disk1s1 (disk1s1) <not mounted>: 209.7 MB
  Untitled 1 (disk1s2) /Volumes/Untitled 1: 7.97 GB (7.93 GB free)
  Recovery HD (disk1s3) <not mounted>: 650 MB
  Apple, Inc. Keyboard Hub
  Apple Inc. Apple Keyboard
  Apple Computer, Inc. IR Receiver
  AKM              AK5370          
  Apple Inc. BRCM2046 Hub
  Apple Inc. Bluetooth USB Host Controller
Gatekeeper: ?
  Anywhere
Kernel Extensions: ?
  [loaded] com.iospirit.driver.rbiokithelper (1.7.2) Support
Problem System Launch Agents: ?
  [failed] com.apple.CalendarAgent.plist
  [failed] com.apple.tccd.plist
Launch Daemons: ?
  [loaded] com.adobe.fpsaud.plist Support
  [loaded] com.bombich.ccc.plist Support
  [loaded] com.microsoft.office.licensing.helper.plist Support
  [loaded] com.oracle.java.Helper-Tool.plist Support
  [loaded] com.oracle.java.JavaUpdateHelper.plist Support
Launch Agents: ?
  [loaded] com.oracle.java.Java-Updater.plist Support
User Launch Agents: ?
  [loaded] com.citrixonline.GoToMeeting.G2MUpdate.plist Support
User Login Items: ?
  Dropbox
Internet Plug-ins: ?
  Flip4Mac WMV Plugin: Version: 3.0.0.126   - SDK 10.8 Support
  FlashPlayer-10.6: Version: 14.0.0.145 - SDK 10.6 Support
  JavaAppletPlugin: Version: Java 7 Update 65 Check version
  Flash Player: Version: 14.0.0.145 - SDK 10.6 Outdated! Update
  RogersOneNumber_68286: Version: 1.0.68286 - SDK 10.5 Support
  QuickTime Plugin: Version: 7.7.1
  SharePointBrowserPlugin: Version: 14.4.1 - SDK 10.6 Support
  Silverlight: Version: 5.1.20125.0 - SDK 10.6 Support
  iPhotoPhotocast: Version: 7.0 - SDK 10.8
Audio Plug-ins: ?
  AirPlay: Version: 1.7 - SDK 10.8
  iSightAudio: Version: 7.7.1 - SDK 10.8
iTunes Plug-ins: ?
  TuneUp Visualizer: Version: (null) Support
  Quartz Composer Visualizer: Version: 1.4 - SDK 10.8
User Internet Plug-ins ?
  CitrixOnlineWebDeploymentPlugin: Version: 1.0.105 Support
3rd Party Preference Panes: ?
  Candelair  Support
  Flash Player  Support
  Flip4Mac WMV  Support
  Java  Support
  MacFUSE  Support
  Tuxera NTFS  Support
Time Machine: ?
  Skip System Files: NO
  Mobile backups: OFF
  Auto backup: YES
  Volumes being backed up:
  Mac Mini HD: Disk size: 698.32 GB Disk used: 263.01 GB
  Destinations:
  Data [Network] (Last used)
  Total size: 2 
  Total number of backups: 162
  Oldest backup: 2012-01-06 09:53:34 +0000
  Last backup: 2014-08-14 02:24:59 +0000
  Size of backup disk: Adequate
  Backup size 2  > (Disk used 263.01 GB X 3)
  Time Machine details may not be accurate.
  All volumes being backed up may not be listed.
Top Processes by CPU: ?
      51% CalendarAgent
      4% WindowServer
      4% syslogd
      3% Dropbox
      1% activitymonitord
Top Processes by Memory: ?
  434 MB WebProcess
  156 MB PluginProcess
  115 MB mds
  90 MB ReportCrash
  90 MB Finder
Virtual Memory Information: ?
  5.08 GB Free RAM
  1.76 GB Active RAM
  103 MB Inactive RAM
  822 MB Wired RAM
  561 MB Page-ins
  0 B Page-outs

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