Problem sending photos from iPhone.

I am rying to send pictures to my personal home and work email accounts and get a "rejected by the server because it does not allow relaying" message.

After talking with my e-mail service provider I understood some more configurations, which might help you to help me:
SMTP Settings:
Authentication method: encrypted password
Connection Security: STARTTLS
How can I copy these settings into my iPhone 5S? In Authetication there's only the following options:
Password, MD5 challenge-response, HTTP MD5 Digest and NTLM...
Thank you!
Best regards,
Pedro Santos

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