Problems with IPhone 4S and pop email

Hi
I'd be very grateful if someone here is able to help me
I recently bought an IPhone 4S and am having problems with the two pop email accounts I need to put on it.
When I use these settings below (sent to me by my web hosting company) I get the message
The POP server "mail.myemailaddress.com" is not responding. Check your network connection and that you entered the correct information in the "Incoming Mail Server" field
When I try and send out emails I get the message
Cannot Send Mail
The connection to the outgoing server "smtp.myemailaddress.com" failed
I've also had the message
CANNOT SEND MAIL
a copy has been placed in your outbox. The recipient (email address) was rejected by the server because it does not allow relaying.
Settings I've put in are
Pop Account
Incoming mail server
Host name  mail.myemailaddress
User name  my email address
Password    my password
Outgoing
SMTP smtp.myemailaddress
Advanced
Use SSL off
authentication - password
server port 25
I've also tried using port 26, port 110 and port 995 with SSL enabled and no luck with any of them
I've contacted my web hosting comapny but they can't help so anyting suggested here will be very gratefully received

Some folks think the problem is due to poor solder connections of the WiFi chip on the card. Heating may expand the joints to cause temporary connectivity. The chip itself could be of low tolerance, and the iOS update causes it to fail the threshold. If you have tried the software resets, then the cure is to reflow the solder of the chip to the WiFi card, or to replace the WiFi card. Apple will not "own" this problem, even though it seems to be widespread. Apple offers to renew your contract for a new iPhone at $199. Certain repair shops will tackle this problem, although many local shops will not. In the US try iFix Miami Beach. See them on eBay <http://www.ebay.com/itm/iPhone-4S-Grayed-Out-Wifi-Wireless-Fix-Repair-Service-Tr usted-Specialists-/161160765436?ssPageName=ADME:L:OU:US:1120> for a $69 fix. They fixed my iPhone 4S and returned within a week (even over the Memorial Day holiday weekend). In Europe, I have read about, but have not tried PodMod <http://www.podmod.org>

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