Restiction of material types based on the industry sector?

I have developed  specific industry sector for my client and also developed specific material types (Z*) for them.         
But then i cannot prevent my user from creating the material master with the incorrect industry sector and also they are able to create material types choosing the incorrect material type?
Can somebody please advise how to restric this.
Thanks
Regards

In the MM01 trxn ..
Enter Industry sector & Material Type.
then Click > Defaults > Industry Sector > Put tick to Industry sector ..
So, that the Z* Industry sector will become Default..
As user will not see Industry sector , there is no Question of changing..
Pls do it for All Users..

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