Safari keeps asking for Keychain Access

Everytime I use Safari after some time it asks for Keychain access. I disabled the autofill forms feature already, but it does not stop asking. Does anybody know how to keep Safari from doing this without disabling the password protection of my keychain?
Honestly said, this erraneous behaviour keeps me from using Safari as Firefox does not make such strange attempts to use Keychain.

I didn't think before reading this discussion to be related, but now I tend to believe it may be. I've recently started using Papers.app and to get access to some publications under institutional subscription I have to configure both Papers.app and Safari to be authenticated connecting to Internet through my institution's proxy. The problem is that now the keychain access manager keeps asking authorization every now and then what really has become a heavy nuisance, not only occurring while a keep Safari open, but also while using any other application which try to connect to the Internet such as iTunes or Fission.app. Before I started using Papers.app I had devoted one browser to download articles nder subscription in order to limit such nuisance to the time I was browsing them. However, using Papers.app I've been forced to configure Safari to that purposes, reproducing the annoying effects every time I open any application which are connecting to the Internet. I posted a message in the Papers.app but nobody has replied so far. I thought of changing the browser used by Papers.app would help, unfortunately, I couldn't find any way to get so. Now that it seems there is a way to prevent the system from asking for keychain access, it may fix the problem. This is the message I posted in Papers' Support Forum. I'd really appreciate any help or suggestion:
Can Papers.app use a different browser other than Safari to get authentication from my institution's proxy?
I am at the University of Barcelona (UB), Spain, we also have an automatic proxy-cache configuration URL (like johnraekwon at the U of Manchester)
http://www.bib.ub.edu/pac/proxy.pac
Every time I open the browser I've configured to connect through your University proxy, I get a drop down menu to authenticate with and then I proceed to the URL I head to, only now with UB credentials. More or less like johnraekwon has to do.
Unfortunately this aunthentication doesn't last for long, you are often requested to authenticate again and again. This nuisance made me decide to devote a browser different from the default browser to download articles, and it's being working rather satifactorily while I only used that browser to download papers from the Internet.
Now that I tried configuring Papers.app to download those articles which requiring subscription I've found that it only works as long as Safari is configured in the same way, that is, it has to authenticated by the proxy to get access to the Internet. I wouldn't mind using Safari exclusively to browse papers. The problem is that most other applications are also using Safari as default browser and it doesn't seem it can be changed, among them iTunes, which I usually open to download podcasts. Since I've configured Safari to get access through my institution's proxy, it keeps asking me to authenticate, and halting every task in process by doing so.
For most purposes I don't need to get authorized access, so I wish my default browser not being configured in such a painful manner.
I'd like to know whether I can change some of Papers.app options to replace Safari as default browser by, I say, Firefox, therefore limiting those repetitive authentications to just the time I'm browsing papers. It let Safari idle to be configured as a default browser to smoothly work for other purposes such as iTunes.
Thanks for the interest. Any idea will be welcomed.

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