Serial # does not work. Chat is always unavailable.

Hello,
1. I bought Adobe Creative Suite 5 Design Standard in 2010.
2. I have not tried to initiate Adobe Premiere until now.
3. The serial number I had originally does not work.
4. I have already contacted help (from the registration screen) and received a new serial number. It also does not work. I have tried very carefully.
5. Support chat has been unavailable repeatedly over two days.
Any suggestions? Thank you

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