Software update won't open, or App Store, and Mail won't let me select messages.

Hello,
Moutain Lion is playing up on my machine. Software update won't open, or App Store, and Mail won't let me select messages. Everything else takes at least 20 seconds to open fully.
Any ideas on what to do here?
Cheers,
George
Spec:
Processor  3.4 GHz Intel Core i7
Memory  12 GB 1333 MHz DDR3
Graphics  AMD Radeon HD 6970M 2048 MB
Serial Number  DGKGG1HTDHJW
Software  OS X 10.9 (13A603)

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