Some programs won't launch from menu/desktop - XFCE

I've recently installed a few programs for my desktop - mainly Anki, and MDM login manager. They installed fine, and as most programs do - produced a menu app for it. But for some odd reason, no matter if I try to access it by the XFCE menu, or even creating a desktop icon for it; the program will not launch. Nothing happens. On the other hand, if I launch the program through the terminal I have no issues. It's more of an annoyance than it is a huge problem, but if anyone could help me fix this I'd really appreciate it.
As a side note, it's not an issue of logging out and back in as this has been an ongoing problem for about a week of logout's/reboot's/shutdown's, etc. I'm not sure what kind of information you would need to help diaognose this, so if I can provide anything else of use, please let me know.

For Anki - Both .desktop and terminal command is the same. When trying to launch it with run in terminal, it complains of an untrusted application launcher. I have the choice to launch anyways, or mark as executable. After marking it as executable, the terminal appears for a brief second, then disappears with nothing else.
MDM Launcher - The .desktop is different - pkexec /usr/bin/mdmsetup - where I just type mdmsetup in terminal. When clicking to run in terminal, a polkit authentication pops up in the terminal with sudo and asks for permission to run, and my password. After I type it in, it disappears and nothing launches. If I go into a terminal and choose the same as the the .desktop, the authentication pops up, I repeate the process but this time I get this error: "(mdmsetup:3766): Gtk-WARNING **: cannot open display:"

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