Strange color setting not saving correct color

I am completely baffled why this is happening. I make a simple photoshop document with the color #OF457C and do a 'save for web' and save it as a jpeg at 100%. I then open it back up from my desktop and the color has darkened and changed the hex value to #10447D. Its darker and not the correct color for my background.
Try it for yourself. Is it a color profile thing? I am using CS4 but have noticed this happening on CS3 on another computer. Does the 'save for web' pick an alternative color? I've never seen a color shift like this before.

I believe save for web uses sRGB, so if you are working in sometihng else, the conversion could cause a color shift.

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