The email server didn't recognize your username/password combination.

OS: OS X Mavericks
iPhoto: iPhoto v9.5.1 (902.17)
I choose a photo, select Share, select Email, enter an email address to send to and click Send - then I get this error: "The email server didn’t recognize your username/password combination."
In iPhoto preferences I have "Email photos using" set to "iPhoto"; I have an account added for Gmail (outgoing mail server: smtp.gmail.com; Port: 587; User Name and Password are correct for my gmail account, Use SSL is checked - basically everything is default for when I chose to add a gmail account and I'm positive my user name and password are entered correctly). I do not have 2-step verification enable for my gmail account (I've been searching for a solution online and noticed others mentioned this - this does not apply to my situation).
Please help! What is going on? I just want to send an email from iPhoto using my gmail account.
Thanks!

Thanks again for responding, MrHoffman; my responses to your questions are below in italics:
Have you tested the Gmail account via Apple Mail.app, and does both sending and receiving work?
Yes, I have tested the Gmail account via the Apple Mail.app - sending and receiving work just fine.
Have you confirmed that the Gmail user and password work with the Gmail web interface?
Yes, I am sure it is the correct username and password; I am able to access the Gmail account via the Gmail web interface.
Are you aware of and familiar with both sets of credentials present within each account within Mail.app?  In particular, have you gotten to the configuration displays the SMTP server settings?  (Mail > Preferences > Accounts > Account Information > Outgoing Mail Server (SMTP) > select Edit SMTP Server List > select the SMTP server account > edit the SMTP server settings.)
I'm not sure what you mean by both sets of credentials, but yes, in the Mail.app I have set the Outgoing Mail Server (SMTP) to Gmail (and used the Edit SMTP server list... option to set the smtp server to use default ports, use SSL, and use "Password" authentication (again with my correct username and password for the Gmail account). I also have the Account Information in Mail.app set for the incoming mail server (maybe that's what you mean by both). Either way, I believe having these settings for incoming mail server and outgoing mail server are allowing me to send and receive email for this Gmail account through Mail.app.
I've also had some success by launching Keychain Access.app and finding all passwords associated with the account — specifically and only the Gmail account, in this case — and removing them from your keychain.  This does mean you'll have to re-add those passwords — using Mail.app and no other applications — and see if things start working.
I just tried this - I launched Keychain Access.app and removed all entries associated with Gmail. I opened Mail.app, re-entered my password info, and sent a test email to another account - this worked. I opened iPhoto.app, re-entered my password via the Preferences, selected a photo, selected share, selected email, entered a to: address and clicked send - this didn't work (same error message as before (The email server didn't recognize your username/password combination).

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