This message could not be delivered?

I bought a .Mac account and it set up everyone on my computer automatically. When I open Mail and try to send mail I get an error message saying:
This message could not be delivered and will remain in your Outbox until it can be delivered.
The connection to the server "smtp.mac.com" on port 25 timed out
I can receive mail just fine, but I'm having this issue sending out mail. Any help would be appreciated.

Some ISPs block access to SMTP servers other than their own to reduce the amount of spam sent from their networks; outgoing SMTP traffic uses port 25. Either contact your ISP, use your ISP's mail server, or use a webmail service to send mail.
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