TS3899 Sending emails from some WI-FI locations

I can send and receive emails in most WI-FI's yet once in a while I have trouble sending emails from some WI-FI locations, even though I can receive all emails and everything else works 100% too.  If I leave this WI-Fi and if I were to go to an Apple store for example, it will then send all emails in Outbox that will not send from this WI-FI . 
What setting prevents sending emails from the few WI-FI!s that emails do not work.

You're welcome.
Please answer the question - is the account's SMTP server authenticated with the account's user name and password?
Regardless, this has nothing whatsoever to do with the iPhone and once again, receiving email and sending email with an email client are completely separate processes. All ISPs block the use of SMTP servers that are outside of their network or not provided by the ISP being used for your internet connection at the time unless the SMTP server is authenticated. This is part of an overall effort to prevent spam eminating from the ISP's domain. Rarely if ever is there any restriction on receiving email regardless the ISP being used for your internet connection.
The email account provider associated with the few wi-fi networks with the problem may restrict the sending of email with any SMTP server regardless if the SMTP server is authenticated.

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