Unable to eject external USB hard drive

I've been using a 500 gb WD Passport external USB hard drive for about six months now, and recently it's had trouble ejecting. I'm not sure if it's the drive itself or my OS; sometimes I can eject it, other times I get the "the disk __ wasn't ejected because one or more programs may be using it.".
There are NO programs using the drive, and no users connected to the drive from elsewhere. Is there some process in the activity monitor that may be preventing the disk from unmounting?
I've tried to log out, relaunch the finder, quite all programs, etc - but the only sure fire method is to restart the computer - which leads me to believe there is some underlying system process that is causing the eject sequence to hang...
Any ideas? Will I potentially harm my disk's contents by force ejecting every time (so long as I'm certain no programs are writing files)?
Thanks!

I'm aslo having problems with a USB drive. In this case it's my Time Machine drive. Similar symptom that the only way to eject it is to restart the computer. Otherwise I get the same message. I also tried the Terminal command with the drag/return. What showed was an empty command line:
+ip-109-43-193-109:~ user$+
Now, the reason why I've even tried to do this is because I'm having problems backing up withTime Machine. Upon boot up, the first backup always works, but typically any subsequent b/up will fail with the following error code:
+Starting standard backup+
+Backing up to: /Volumes/Jimz TM 2/Backups.backupdb+
+Error: (22) setxattr for key:com.apple.backupd.ModelID path:/Volumes/Jimz TM 2/Backups.backupdb/user's MBP size:13+
+Error: (-50) Creating directory 2010-07-08-112436.inProgress+
+Failed to make snapshot container.+
+Error: (22) setxattr for key:com.apple.backupd.ModelID path:/Volumes/Jimz TM 2/Backups.backupdb/user's MBP size:13+
+Backup failed with error: 2+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
+Stopping backupd to allow ejection of backup destination disk!+
Also, this is the first time that I've seen the error lines regarding ejection of the disc.
Thanks in advance for any thoughts on this.

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