Unable to export from iPhoto to other location

Would appreciate any help and guidance with above please.
I don't normally use iPhoto but I have a couple of photos' I'd like to transfer to my Pictures folder.
When I select Export function, I select the desired location and click the Export button. A small ' exporting ' window pops up with a flash of the blue and white chevron (doing something ) strip followed by a statement ' unable to create/users/names/pictures.
Probably doing something wrong.
Thanks & regards

Unsure as to how but I've obviously done something wrong..it does help to read the book first!
However, other images in iphoto export ok,email ok and I have imported into iphoto and then exported back so everything does seem to be working ok.
I've obviously messed up somehow with about 5 particular images that'll I'll put down to user error!!
Thanks for prompt response Terence and have given you a green tick for making me look further. Should have tried that in the first place.
Thanks again, regards John

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