Upgrading to Maverick causing problems

I recently upgraded my operating system to Maverick.
Since then my time machine back up disk won't back up due to lack of space, which wasn't previously an issue and my Mac won't shut down properly just goes to blank white screen and freezes.
Not sure if the two things are linked or what's causing the problem.
Any suggestions and help gratefully received

Thanks for your patience, this is all new to me. Think this is what you requested. Really appreciate your help
14/07/2014 14:13:45.797 com.apple.backupd[796]: Backing up to /dev/disk1s2: /Volumes/Untitled/Backups.backupdb
14/07/2014 14:13:51.775 com.apple.backupd[796]: Event store UUIDs don't match for volume: Macintosh HD
14/07/2014 14:13:51.795 com.apple.backupd[796]: System files exclusion changed.
14/07/2014 14:13:52.492 com.apple.backupd[796]: Deep event scan at path:/ reason:must scan subdirs|new event db|
14/07/2014 14:18:47.288 com.apple.SecurityServer[14]: Killing auth hosts
14/07/2014 14:18:47.288 com.apple.SecurityServer[14]: Session 100017 destroyed
14/07/2014 14:20:27.020 com.apple.backupd[796]: Finished scan
14/07/2014 14:20:27.020 com.apple.backupd[796]: Not using file event preflight for Macintosh HD
14/07/2014 14:22:15.190 WindowServer[94]: _CGXSetWindowBackgroundBlurRadius: Invalid window 0xffffffff
14/07/2014 14:22:15.328 WindowServer[94]: CGError post_notification(const CGSNotificationType, void *const, const size_t, const bool, const CGSRealTimeDelta, const int, const CGSConnectionID *const, const pid_t): Timed out 1.000 second wait for reply from "loginwindow" for synchronous notification type 102 (kCGSDisplayWillSleep) (CID 0x6e07, PID 41)
14/07/2014 14:22:15.329 WindowServer[94]: device_generate_desktop_screenshot: authw 0x0(0), shield 0x7fcfb0cbd530(2001)
14/07/2014 14:22:15.499 WindowServer[94]: device_generate_lock_screen_screenshot: authw 0x0(0), shield 0x7fcfb0cbd530(2001)
14/07/2014 14:22:15.650 loginwindow[41]: find_shared_window: WID -1
14/07/2014 14:22:15.650 loginwindow[41]: CGSGetWindowTags: Invalid window 0xffffffff
14/07/2014 14:22:15.650 loginwindow[41]: find_shared_window: WID -1
14/07/2014 14:22:15.650 loginwindow[41]: CGSSetWindowTags: Invalid window 0xffffffff
14/07/2014 14:22:16.397 WindowServer[94]: _CGXHWCaptureWindowList: No capable active display found.
14/07/2014 14:22:24.900 loginwindow[41]: CoreAnimation: warning, deleted thread with uncommitted CATransaction; set CA_DEBUG_TRANSACTIONS=1 in environment to log backtraces.
14/07/2014 14:22:41.000 kernel[0]: process backupd[796] thread 75422 caught burning CPU! It used more than 50% CPU (Actual recent usage: 51%) over 180 seconds. thread lifetime cpu usage 245.143820 seconds, (182.109706 user, 63.034114 system) ledger info: balance: 90000747956 credit: 244907605821 debit: 154906857865 limit: 90000000000 (50%) period: 180000000000 time since last refill (ns): 175860511848
14/07/2014 14:22:52.312 spindump[804]: Saved cpu_resource.spin report for backupd version ??? (???) to /Library/Logs/DiagnosticReports/backupd_2014-07-14-142252_Macintosh.cpu_resourc e.spin
14/07/2014 14:24:43.993 xpcproxy[811]: assertion failed: 13E28: xpcproxy + 3438 [D559FC96-E6B1-363A-B850-C7AC9734F210]: 0x2
14/07/2014 14:27:07.015 WindowServer[94]: _CGXHWCaptureWindowList: No capable active display found.
14/07/2014 14:28:00.140 com.apple.backupd[796]: Found 765214 files (42.84 GB) needing backup
14/07/2014 14:28:00.186 com.apple.backupd[796]: 51.63 GB required (including padding), 7.7 GB available
14/07/2014 14:28:00.218 com.apple.backupd[796]: Deleted backup /Volumes/Untitled/Backups.backupdb/Jen’s Mac/2014-07-14-141351.inProgress/EB754333-1284-4FCC-B0A6-4244A1249BAE containing 4 KB; 7.7 GB now available, 51.63 GB required
14/07/2014 14:28:00.218 com.apple.backupd[796]: Removed 1 expired backups so far, more space is needed - deleting oldest backups to make room
14/07/2014 14:28:00.219 com.apple.backupd[796]: Deleted 1 backups containing 4 KB total; 7.7 GB now available, 51.63 GB required
14/07/2014 14:28:00.219 com.apple.backupd[796]: Backup date range was shortened: oldest backup is now Jul 14, 2014
14/07/2014 14:28:01.729 com.apple.backupd[796]: Backup failed with error 7: Not enough available disk space on the target volume.
14/07/2014 14:28:52.063 WindowServer[94]: _CGXHWCaptureWindowList: No capable active display found.
14/07/2014 14:29:44.452 periodic-wrapper[820]: Running weekly periodic task.
14/07/2014 14:29:44.454 periodic-wrapper[819]: Running monthly periodic task.
14/07/2014 14:29:44.678 periodic-wrapper[818]: Running daily periodic task.
14/07/2014 14:31:18.390 WindowServer[94]: _CGXHWCaptureWindowList: No capable active display found.
14/07/2014 14:37:43.306 WindowServer[94]: CGXDisplayDidWakeNotification [13526059534403]: posting kCGSDisplayDidWake
14/07/2014 14:37:43.307 WindowServer[94]: handle_will_sleep_auth_and_shield_windows: Deferring.
14/07/2014 14:37:48.342 loginwindow[41]: CoreAnimation: warning, deleted thread with uncommitted CATransaction; set CA_DEBUG_TRANSACTIONS=1 in environment to log backtraces.
14/07/2014 14:38:09.698 com.apple.WebKit.Networking[249]: ERROR: unable to get the receiver data from the DB!
14/07/2014 14:38:09.699 com.apple.WebKit.Networking[249]: ERROR: unable to get the receiver data from the DB!
14/07/2014 14:38:50.050 Console[948]: setPresentationOptions called with NSApplicationPresentationFullScreen when there is no visible fullscreen window; this call will be ignored.
14/07/2014 14:38:52.292 WindowServer[94]: disable_update_timeout: UI updates were forcibly disabled by application "Console" for over 1.00 seconds. Server has re-enabled them.
14/07/2014 14:38:54.130 WindowServer[94]: common_reenable_update: UI updates were finally reenabled by application "Console" after 2.84 seconds (server forcibly re-enabled them after 1.00 seconds)
14/07/2014 14:41:45.625 WindowServer[94]: disable_update_timeout: UI updates were forcibly disabled by application "Finder" for over 1.00 seconds. Server has re-enabled them.
14/07/2014 14:41:46.107 WindowServer[94]: common_reenable_update: UI updates were finally reenabled by application "Finder" after 1.48 seconds (server forcibly re-enabled them after 1.00 seconds)
14/07/2014 14:41:47.426 com.apple.internetaccounts[232]: *** Entitlement com.apple.private.iaaccounts is missing.
14/07/2014 14:41:47.648 Finder[198]: *** remoteObjectProxyWithErrorHandler failed: Error Domain=NSCocoaErrorDomain Code=4097 "Couldn’t communicate with a helper application."; {

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