Vanishing emails using mail.app

I'm having a weird problem with my iPhone 4 - three times out of four, it will completely fail to send a mail message. This happens with both my Gmail account and work email, and I've triple checked the settings on both and they're definitely correct.
What happens is I'll hit send and the bottom bar changes to "Sending mail...". No error message comes up, but when I go into sent items the mail isn't there, nor does it show up in Outbox or Drafts. It literally disappears into the ether!
It's been going on for a few months now and has been driving me up the wall. However through trial and error I have managed to ascertain the following:
It never happens when I am on wi-fi, only using mobile data
Sparrow works absolutely fine with no issues and I now use it as my Gmail client, but it won't send my work mails - just downloads them. According to our IT guys this is a mail server setting issue, as when I'm connected to the work wi-fi network it works fine
I also cannot upload photos on Facebook mobile using mobile data
I can't upload photos to Twitter via Tweetbot, but can with the official Twitter App
I had to stop using iMessage, as messages would frequently just not arrive on my phone
I'm on giffgaff if that helps. Screengrabs of my network data settings below:
Any ideas? It's driving me MENTAL!

Mac OS X 10.4.7 introduced connection issues in Mail similar to what you’re observing as a result of (according to the documentation) “Mail now supports connecting to mail servers through a SOCKS proxy”. If that’s the problem, it can usually be fixed by going to System Preferences > Network, choosing the network port configuration used to connect to Internet from the Show popup menu and disabling the SOCKS Proxy in the Proxies section, if it’s enabled.
And while you’re at it, choose Network Port Configurations from the Show popup menu, and make sure that the configuration used to connect to Internet appears at the top of the list.

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